Effects of equal‐channel,multiple‐angular extrusion on the physical and mechanical properties of glassy polymers

Through the examples of polycarbonate and poly(methyl acrylate), the evolution of the structure and properties of glassy polymers processed by equal‐channel multiple‐angular extrusion (ECMAE) were studied. It was demonstrated that ECMAE allowed the substantial improvement of the set of strain–strength characteristics of these materials, regardless of the direction of loading applied. With the use of the data from scanning electron microscopy, differential scanning calorimetry, and dilatometry, we found that the simultaneous growth in the strength, plasticity, and impact resistance was related to the formation of a net of biaxially oriented polymeric chains, the decrease in the free volume, and the reinforcement of intermolecular interaction. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42180.     

Phytochemical Characterization of Veronica officinalis L., V. teucrium L. and V. orchidea Crantz from Romania and Their Antioxidant and Antimicrobial Properties

Aerial parts of Veronica species are used in Romanian traditional medicine for the treatment of various conditions like kidney diseases, cough, and catarrh, and are known for their wound-healing properties. In the present study, the phenolic and sterolic content and the antioxidant and antimicrobial activities of three Veronica species (Plantaginaceae), V. officinalis L., V. teucrium L. and V. orchidea Crantz, were studied. The identification and quantification of several phenolic compounds and phytosterols were performed using LC/MS techniques and the main components were p-coumaric acid, ferulic acid, luteoline, hispidulin and β-sitosterol. More than that, hispidulin, eupatorin and eupatilin were detected for the first time in the Veronica genus. Nevertheless, representatives of the Veronica genus were never investigated in terms of their phytosterol content. The antioxidant potential investigated by Trolox equivelents antioxidant capacity (TEAC) and EPR spectroscopy revealed that V. officinalis and V. orchidea extracts presented similar antioxidant capacities, whilst the values registered for V. teucrium extract are lower. Regarding the antimicrobial activity of the investigated species, Staphylococcus aureus, Listeria monocytogenes and Listeria ivanovii were the most sensitive strains with MIC values between 3.9 and 15.62 mg/mL. The results obtained by this study may serve to promote better use of representatives from the genus Veronica as antioxidant and antimicrobial agents.     

Dynamische Verformungsmessungen an Eisenbahnbrücken mittels Mikrowelleninterferometrie

Dynamic measurements of railway bridge displacements through microwave interferometry – Part 1: measurement method The microwave interferometry is a rather new measuring technique, yet little‐known in civil engineering applications. It allows the non‐contact acquisition of structural displacements with accuracy in the sub‐millimetre range at a sampling rate of up to 4 kHz. The high sampling frequency allows also the caption of dynamic structural responses, which can be used for a straightforward determination of the main modal parameters of the structures (natural frequencies, damping ratios). Furthermore, the synchronous acquisition of the overall motion of the targeted object is possible due to a high range resolution, which facilitates a direct identification of modal shapes. This paper gives a short introduction of the measurement method and outlines its boundary conditions and limitations with respect to applications in railway bridge dynamics. The knowledge has been gained on the basis of comprehensive systematic experimental investigations performed within the frame of a cooperation project with the German Railways (Deutsche Bahn AG). As a result an evaluation matrix was created, which clearly illustrates the applicability of the microwave interferometry for different railway‐specific tasks. The second part will present selected results of microwave interferometry measurements of railway bridges in comparison to parallel conventional measurements and the corresponding numerical investigations, which were used for the validation of the measurement technique.     

Relation between the reduction of coal and its fractional composition

Simulation confirms literature data regarding the higher yield of light fractions (density ρ ⩽ 1.28–1.30 g/cm³) from reduced coal than from slightly reduced coal. The predominance of light fractions with an elevated hydrogen content in the coal’s organic mass facilitates the formation of physicochemical properties associated with high degrees of reduction. The degree of reduction is related to the content of such fractions in the coal. This is evidently the case for a whole range of caustobioliths and is especially pronounced for oil, whose value is directly related to the content of light fractions (ρ ⩽ 0.84–0.87 g/cm³).     

Degradation and Mechanical Behavior of Fish Gelatin/Polycaprolactone AC Electrospun Nanofibrous Meshes

With the increasing interest in biopolymer nanofibers for diverse applications, the characterization of these materials in the physiological environment has become of equal interest and importance. This study performs first-time simulated body fluid (SBF) degradation and tensile mechanical analyses of blended fish gelatin (FGEL) and polycaprolactone (PCL) nanofibrous meshes prepared by a high-throughput free-surface alternating field electrospinning. The thermally crosslinked FGEL/PCL nanofibrous materials with 84–96% porosity and up to 60 wt% PCL fraction demonstrate mass retention up to 88.4% after 14 days in SBF. The trends in the PCL crystallinity and FGEL secondary structure modification during the SBF degradation are analyzed by Fourier transform infrared spectroscopy. Tensile tests of such porous, 0.1–2.2 mm thick FGEL/PCL nanofibrous meshes in SBF reveal the ultimate tensile strength, Young's modulus, and elongation at break within the ranges of 60–105 kPa, 0.3–1.6 MPa, and 20–70%, respectively, depending on the FGEL/PCL mass ratio. The results demonstrate that FGEL/PCL nanofibrous materials prepared from poorly miscible FGEL and PCL can be suitable for selected biomedical applications such as scaffolds for skin, cranial cruciate ligament, articular cartilage, or vascular tissue repair.     

Influence of metal-ferroelectric contacts on the space charge formation in ferroelectric thin film capacitors

We have studied the response speed characteristics of capacitor structures based on thin Ba_0.3Sr_0.7TiO₃ (BSTO) films with metal-ferroelectric contacts of various types formed under different conditions. It is established that threshold voltages exist for the appearance of a residual space charge in some structures. A comparative analysis of the technological features of contact formation and experimental data on the characteristics of samples leads to the conclusion that, by forming Pt-BSTO contacts in an oxygen-containing atmosphere, it is possible to suppress the injection of carriers into the ferroelectric film in the capacitor structure.     

Fracture of Gd2 (MoO4)3 single crystals

Fracture behaviour of Gd2 (MoO4)3 single crystal, which is improper ferroelectric–ferroelastic, has been examined by means of point loading. There are three fracture planes in gadolinium molybdat (GMO): ;100} – main cleavage plane, {210} and {110} – secondary cleavage ones. It is shown that cracks have a tendency to transit from secondary planes up to cubic plane and vice versa. This would be considered as the main cause of river pattern appearance on fracture surfaces of samples. Mechanical twinning and crack growth are independent channels for relaxation of elastic energy in GMO, which do not connected between themselves, so excluding of twinning leads to increase of crack length.     

Minimization of free radical damage by metal catalysis of multivitamin/multimineral supplements

Multivitamin/multimineral complexes are the most common dietary supplements. Unlike minerals in foods that are incorporated in bioorganic structures, minerals in dietary supplements are typically in an inorganic form. These minerals can catalyze the generation of free radicals, thereby oxidizing antioxidants during digestion. Here we examine the ability of a matrix consisting of an amino acid and non-digestible oligosaccharide (AAOS) to blunt metal-catalyzed oxidations. Monitoring of ascorbate radical generated by copper shows that ascorbate is oxidized more slowly with the AAOS matrix than with copper sulfate. Measurement of the rate of oxidation of ascorbic acid and Trolox^® by catalytic metals confirmed the ability of AAOS to slow these oxidations. Similar results were observed with iron-catalyzed formation of hydroxyl radicals. When compared to traditional forms of minerals used in supplements, we conclude that the oxidative loss of antioxidants in solution at physiological pH is much slower when AAOS is present.